In: Landolt-Börnstein - Group IV Physical Chemistry, Part 3: Compounds from CoClĤ volume 19 A3. ^ Scientific Group Thermodata Europe (2001): "Thermodynamic Properties of Compounds, CoClģ".Journal of the Chemical Society A: Inorganic, Physical, Theoretical, volume 1966,pages 501-511 doi: 10.1039/J19660000501 Sharpe (1966): "The variations in the thermal stabilities of the trichlorides, tribromides, and tri-iodides of the metals of the first transition series at 50 ☌". Schall (1932): "Zur anodischen Oxydation von Co und Ni‐Dichlorid (Nachtrag)." Zeitschrift für Elektrochemie, volume 38, page 27. Duval (1937): Comptes rendues, volume 204, page 780. Transactions of the American Electrochemical Society, volume 45, page 161. McDermott, and Adelle Bergman (1983): "Infrared spectra of the matrix-isolated chlorides of iron, cobalt, and nickel." Journal of Molecular Spectroscopy, volume 98, issue 1, pages 111-124. Corrosion Science, volume 15, issues 6–12, pages 603-625. Halstead (1975): "A review of saturated vapour pressures and allied data for the principal corrosion products of iron, chromium, nickel and cobalt in flue gases". Zeitschrift für anorganische und allgemeine Chemie, volume 268, issue 1‐2, pages 25-34. ^ a b Harald Schäfer and Kurt Krehl (1952): "Das gasförmige Kobalt(III)‐chlorid und seine thermochemischen Eigenschaften".Inorganic and Nuclear Chemistry Letters, volume 5, issue 4, pages 277-283. (1969): "The interaction of cobalt(III) with chloride ion in acetic acid". Another classical example is tris(ethylenediamine)cobalt(III) chloride Co(H In particular, hexamminecobalt(III) chloride Co(NHģ is the archetypal Werner complex and has uses in biological research. Trichlorides of cobalt(III) complexed with various ligands, such as organic amines, can be quite stable. In solutions of cobalt(III) salts with chloride ions, the anionic complexes (H The hexachlorocobaltate(III) anion CoCl 3−Ħ has been identified in preparations of cobalt(III) salts and hydrochloric acid HCl in glacial acetic acid. In a 1932 report, the compound was claimed to arise in the electrolysis of cobalt(II) chloride in anhydrous ethanol. Ī report from 1969 claims that treatment of solid cobalt(III) hydroxide CoOOHĢO with anhydrous ether saturated with HCl at −20 ☌ produces a green solution (stable at −78 ☌) with the characteristic spectrum of CoCl Ĭobalt trichloride, in amounts sufficient to study spectroscopically, was obtained by Green and others in 1983, by sputtering cobalt electrodes with chlorine atoms and trapping the resulting molecules in frozen argon at 14 K. At 1073 K, the partial pressures were 7.3 and 31.3 mm Hg, respectively. However, equilibrium shifts to the left at higher temperatures. The trichloride is formed through the equilibriumĪt 918 K (below the melting point of CoClĢ, 999 K), the trichloride was the predominant cobalt species in the vapor, with partial pressure of 0.72 mm Hg versus 0.62 for the dichloride. Preparation Ĭobalts trichlorides was detected in 1952 by Schäfer and Krehl in the gas phase when cobalt(II) chloride CoClĢ is heated in an atmosphere of chlorine ClĢ. Īerodynamic properties for the gas phase have been determined by the Glushko Thermocenter of the Russian Academy of Sciences. Ī Scientific study of the stability of this and other metal trihalides at 50 ☌ was published by Nelsoon and Sharpe in 1956. The infrared spectrum of the compound in frozen argon indicates that the isolated CoClģ molecule is planar with D 3h symmetry. Those earlier reports claim that it gives green solutions in anhydrous solvents such as ethanol and diethyl ether, and that it is stable only a very low temperatures (below −60 ☌). Some articles from the 1920s and 1930s claim the synthesis of bulk amounts of this compound in pure form however, those results do not seem to have been reproduced, or have been attributed to other substances like the hexachlorocobaltate(III) anion CoCl 3−Ħ. It has also been found to be stable at very low temperatures, dispersed in a frozen argon matrix. The compound has been reported to exist in the gas phase at high temperatures, in equilibrium with cobalt(II) chloride and chlorine gas. In this compound, the cobalt atoms have a formal charge of +3. Cobalt(III) chloride or cobaltic chloride is an unstable and elusive compound of cobalt and chlorine with formula CoClģ.
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The reality: The flight actually carried Canadian businessman and “Shark Tank” investor Robert Herjavec. The speculation was that it was Shohei, headed east to sign with the Blue Jays. Witness the frenzy over the flight of a private plane from John Wayne Airport to Toronto on Friday afternoon. They maintained the cone of silence all the way up to the moment of Ohtani’s Instagram post, which could be considered the 2023 version of LeBron James’ “The Decision” TV special.Ī post shared by Shohei Ohtani | 大谷翔平 lack of information produced hype in its own way, again thanks to social media. This was obviously a smashing triumph for Ohtani and agent Nez Balelo, who managed the free agency process masterfully from their end. They didn’t do it last August and it bit them in the postseason. Meanwhile, Dodgers president of baseball operations Andrew Friedman and general manager Brandon Gomes still need to add a starter or two this winter. Neal ElAttrache of the Kerlan-Jobe Institute, performed the procedure.Īnd while the value of one guy who can perform two full-time tasks might be incalculable, this could be as close as we get to a true estimate of what that phenomenon is worth. With such a humongous contract for a position player, often the first reaction is, “Yeah, but can he pitch?” Ohtani won’t be a full two-way player again until 2025, following his second Tommy John surgery in six years in September, but I have to think that the Dodgers came away convinced that pitching effectively is again in his future – especially since their team physician, Dr. Decades from now, people will refer to a “Shohei Ohtani” contract, almost certainly in less sarcastic terms. And they did so creatively enough – with, according to SCNG beat writer Bill Plunkett, a whopping $680 million of the $700 million deferred to after the expiration of the contract – to add the best player in the world to an already potent lineup without sending their payroll soaring past the luxury tax limits.Īnd consider: Now, we laugh when Bobby Bonilla gets his yearly payment from the New York Mets. Just because the Dodgers have the ability to pay beyond market value, or to sign a star to a lengthy, lucrative contract, doesn’t mean they’re always willing to do so.īut they made a long-term commitment to acquire a player that the organization had pursued since he was in high school in Japan. That he agreed to sign with the Dodgers shouldn’t have been a huge surprise, although I was dubious that he would. Thus explains the massive shock that accompanied Saturday’s word of Shohei Ohtani’s next destination, and particularly the record-setting price tag it took to get him to switch his workplace from Anaheim to Los Angeles: $700 million over 10 years. That’s how we keep score, even as so many who follow baseball turn themselves inside out when another player scores a big contract. Our family is forever grateful for our Candela community, and we cannot explain how much your help means to us.It’s always about the money, actually. If we are so fortunate to count on your patronage and support we can pass along the love to these incredible employees who have helped keep the restaurant industry in Los Angeles running from behind the scenes for the last 43 years. Independent restaurants directly employ 11 million people and indirectly employ millions more through a vast supply chain. With your help, we will be creating and distributing care packages that include groceries and essential items to our staff, and those back of house employees in the restaurant industry who have lost their jobs during this time and are in dire need of essentials. We have seen the power of what we can do together, and during this difficult time, we need the help of our community more than ever, so we can continue supporting our staff, their families, and others in the restaurant and event industry that are in need during this difficult time.Įvery donation helps as these funds will directly benefit our team members who cannot support themselves or their families right now. Unfortunately, it wasn't enough and we have completely shut down. We never imagined having to close our doors, and even tried to operate as a takeout-only business to avoid having to lay off our staff. Candela La Brea is a family-owned business that has proudly served the Los Angeles community for over 40 years, guided by our core values of community, family and giving back. I just purchased a reloop mixtour as my mini controller with transport controls. New and looking for advice? /r/Beatmatch.r/Beatmatch - for learning to DJ! /r/Controllerism /r/DJsCirclejerk /r/DJSetups /r/EDMproduction /r/Mixes /r/MobileDJ /r/RotaryMixers /r/SoundSystem /r/Turntablists /r/VinylDJs /r/VJing /r/WeAreTheMusicMakers /r/WhiteLabelsĬommunityWalk Map - Map of r/DJs members! > Unofficial DJs Discord <- Also check out PLEASE REPORT posts and comments that violate the above rules or just suck. Posts asking “what should I play for this gig?”.Obvious spam for youtube channels/gig logs/blogs/advertisements.Support the people who make your hobby/career possible. Posts discussing music piracy (in the sense of people asking how where or how to pirate music, if you want to have an actual discussion on piracy and how it pertains to the industry, by all means).Self-promotion posts including mixes, tunes, events, companies, etc.The following topics are against sub rules and will be deleted: Gig pictures/Stories - should be posted in the weekly gigs thread We will also allow high profile posts - say if a regular user gets a feature mix on DJCity or a Serato sponsored set or a established DJ set. Mixes - Most mix posts will be deleted although short routines, showcasing of interesting technique, and videos that shows off the poster doing something cool is fine. Meme/Humor/crappy image posts belong in /r/DJsCircleJerk. Please ensure you are posting to the correct subredditĪny and all beginner questions and posts should be made in /r/Beatmatch. Trolling, slapfights, general assholery is not encouraged and it also goes without saying that racist, sexist, homophobic, and transphobic posts and language will not be tolerated at all.Please try to be polite, friendly and helpful when commenting.There is also an entire subreddit /r/Beatmatch dedicated to helping new DJs learn. If you are new and are interested in learning how to DJ please check out this thread first. r/DJs is a subreddit for general DJ discussion: equipment, techniques, news, music, etc. Provide supports batch editing of most common audio file types.An impressive application to edit metadata of audio files faultlessly.Taking everything in consideration, Metadatics is a magnificent application to edit metadata of audio. You can also read and write ID3v1, Vorbis, APE, ID3v2, MP4, and ASF tags all from a variety of audio file types. Metadatics enables you to rename your files and generate directory structures based on your file’s metadata. It provides full support for album artwork and multiple images to become more efficient. The software allows you to generate a sequence of numbers and also copy from tag to tag. You may also like Export for iTunes for Mac Free Download It has a number of built-in functions that allow you to replace text, view metadata, and perform other changes accordingly. You can easily edit thousands of audio files at once without putting in any special efforts. The application offers support for batch processing which saves your precious time. It comes with a modern-looking user interface that anyone with basic computer skills can use. This impressive application provides support for all the major audio file formats like MP3, M4A, APE, OGG, WMA, AIFF, WAV, FLAC, and more. Metadatics is one of the software solutions that let you edit audio files in an enormous way. System Requirements for Metadatics for Mac.Technical Details of Metadatics for Mac.It will then be displayed properly in the Naim app from the get go. One other observation that is perhaps not surprising - when importing a downloaded album into the Innuos for the first time, be sure that the art work filename is changed to folder.jpg. If I reversed the change just made, the Naim app would go back to showing only an icon in the album list, but would show the art work when the album is opened and show the art work beside each track. Voilà! The album art is now displayed in the Naim app. I also had to use the Innuos app to change something in the metadata - a single character change in the title seems to work - and then save the change. However, simply changing the filename, even if the Innuos library is rescanned and the image cache and UPnP cache of the Naim app are cleared, does not by itself solve the problem. All of the albums where the artwork would display in the Innuos app but not in the Naim app had a filename other than this. This should work for an Innuos music server with the Naim app not sure how it would work with other servers or network attached storage.Īs noted earlier in the thread, the album art needs to be in the appropriate folder on the server with the filename “folder.jpg”. I’ve managed to get all of the recalcitrant albums to show their album art in the Naim. I assume that this would simply force the app to reload art from the web or the server - but you know what they say about “assume”. I started to do this, but stopped at the message warning that this would delete all image data from the device. In another thread, someone mentioned clearing the Naim app image cache in dealing with a similar problem. I’ve made a copy with the name “folder.jpg”, but this doesn’t change anything on the Naim app. I have noted that the filename for one piece of art that does not display on the Naim app is “album_art.jpg”. For all the albums where art is not displayed on the Naim app, it is displayed in the Innuos app. If the Innuos app does not find album art when the download is imported, I can search for it using the bar code (if available) or use a jpg from the local drive or network. I can edit metadata on my PC using the Innuos app. As I hoped, there are some nuggets to work on. Thanks in advance to anyone who can give some insight. I’m wondering if the Naim app can only edit metadata if the UPnP server is a Naim Core? Clicking the three dots in the upper right of an album screen, as suggested in another thread, offers a choice to play the album, move it to the front or rear of a queue, or add it to a playlist there is no option to edit metadata. However, I don’t see any capability to do this. jpg file and is displayed when viewing the music library through the Innuos app.Ī query to Naim support returned the suggestion that one could edit the metadata in the app. The art is present on the Innuos Zen server as a. Often an album where the album art displays and one where it does not are similar, e.g., downloaded from the same label. There does not seem to be any pattern in the albums for which this happens. On a few downloaded albums the Naim app shows the UPnP icon or similar simple graphic instead of the album art. Music is stored on an Innuos Zen Mk II server. I am using the latest version of the Naim app to control an NDS. I thought I would throw this out to the community to see if anyone else as encountered this problem and possibly found a solution. Although doctors can’t always pinpoint what triggered the condition, the culprits can range from viral infections to chest injuries. But he did the right thing, coming in.”ĭoctors don’t expect patients to be able to tell the difference between a heart attack and a pulled chest muscle, she says, but a good rule of thumb is that if you can press on the wall of the chest and it feels even more painful, it’s more likely to be a musculoskeletal injury than a problem with your ticker.Īn estimated 13% to 36% of adults who show up to the emergency room or their doctor’s office with acute chest pain are diagnosed with costochondritis, or inflammation where a rib bone meets up with the cartilage, according to a 2009 review in the journal American Family Physician. “After taking his history, I learned he had moved and hadn’t lifted heavy furniture in years. “I had a patient who came in with chest pain and he was worried he was having a heart attack,” she says. It’s possible for someone to mistake a strained chest muscle for something more serious, like a heart attack, says Dr. What are heart failure, heart attack and cardiac arrest? What causes a heart attack? Cholesterol is a big factor CNN Weekend warriors, take note: If you haven’t lifted anything heavier than a MacBook for more than a few years, you might want to rethink that CrossFit class you signed up for. Left untreated over time, GERD can cause asthma, chest congestion, and a condition called Barrett’s esophagus, which may increase your chances of developing a rare type of cancer. The occasional reflux is fairly common and probably nothing to worry about, but if you’re experiencing it twice a week or more, you may have gastroesophageal reflux disease (GERD). (Our stomachs are lined with protective membranes that shield it from the corrosive effects of acid, while our esophagus does not.)ģ1 Superfood Secrets for a Long and Healthy Life Stomach acid is highly acidic, hence, the burning sensation behind your breastbone on the pH scale, it scores about a 2 (PDF), falling somewhere between battery acid and vinegar. Gastroesophageal reflux occurs when a person’s stomach contents – including the gastric acids that help break down food – back up into the esophagus, the tube that connects the throat and stomach. You might be wondering how someone could mistake the symptoms of acid reflux for a heart attack, but there’s a reason why it’s called heartburn, after all.įor decades, women had heart attacks in silence Here are seven conditions that can cause chest pain – and what everyone should know about to treat them. “As a physician, I would much rather let someone know that it’s nothing to worry about than have someone too late and has permanent damage,” Dr. “I know of one person who died and the last thing in their search bar was ‘heart attack symptoms,’” says Sharonne Hayes, a cardiologist at the Mayo Clinic in Rochester, Minn.Ĭhristine Jellis, MD, PhD, a cardiologist at Cleveland Clinic, seconds that. spoke to three leading cardiologists across the country, and all of them reiterated one thing: If you’re having chest pain, and you’re not 100% sure what’s causing it, either call your doctor or call 911. Some of them – like that chest muscle you pulled raking leaves last fall – are more annoying than serious. Chest pain isn't necessarily from a heart attack, but it can still be seriousĭoctors urge: If you're having chest pain and don't know why, get medical attentionĪll too often, the mention of chest pain conjures up images of a heart attack, but there are plenty of other diseases and conditions that can trigger this symptom. When exporting a Markdown snippet as HTML or plain text, the associated attachments are now also included.Īlfred workflow now supports Alfred Universal Action. The app now automatically selects the matching fragment when searching and performing actions in SnippetsLab Assistant. Improved full text search algorithm to provide more relevant results. Improved brackets and quotes autocompletion.Īdded an option to disable highlighting code blocks without explicit languages in Markdown preview.Īdded the ability to drop files directly into the editor to insert as attachments. The app now automatically trims surrounding whitespaces when entering tags. Global default language now works correctly with SnippetsLab Assistant.įixed an issue where the cursor may not display correctly over line numbers.įixed an issue where not all text files are selectable when importing plain text files.įixed an issue where newly created fragments ignored the global default language setting.įixed an issue where rich content copied from other apps may be unexpectedly pasted as image attachments.Īdded more than 600 new symbols for folders and smart groups. Improved syntax highlighting for various languages. The notes area now uses the same font size as the main editor. SnippetsLab Assistant now has the same sorting behavior as the main window. Improved the accuracy of scroll sync between the Markdown editor and preview. Substantially improved the performance of Markdown preview. Now you can specify seperate actions for click, option-click and command-click.Īdded integrated search bar for Markdown preview. The app now remembers the setting for whether to publish a gist as secret by default.Īdded the command modifier key for assistant actions. When importing from Quiver, images are now automatically converted to Markdown image links. You can now export non-Markdown snippets as HTML as well. The share menu now includes additional options such as exporting as various formats and publishing to GitHub. The Markdown editor now supports rich text styles and automatically applies appropriate font size, weight, style, background color, and more.Īdded 33 new languages including Arturo, Berry, Carbon, CSSUL4, COMAL-80, Cplint, Dax, Fift, FunC, GAP session, JMESPath, Jsonnet, K, MCFunction/MCSchema (minecraft), MediaWiki Wikitext, MIPS, Macaulay2, Phix, Portugol, PostgreSQL Explain, Q, Qlik, SNBT, Sql+Jinja, Tal, Tl-b, UL4, Unix/Linux config files, WGSL (WebGPU Shading Language), World of Warcraft TOC, Wren, and X++.Īdded the ability to preview the contents of backup libraries. New option to toggle Markdown preview mode on a per-snippet basis, instead of globally Sticky table of content that is always visible and expands when hoveringĬopy button when the mouse is hovering above a code block For example (c) to ©, (tm) to ™, =/= to ≠, etc. GitHub style)Īutomatically convert ASCII symbols into their corresponding special characters. Treat newlines as line breaks (choose between CommonMark vs. Male (hat, boots, trousers and coat) or female (bonnet, shoes, skirt and dress top) Male (hat, shoes, trousers and tunic) or female (earrings, shoes, skirt and tunic) Male (boots, pagri, top and trousers) or female (boots, pagri, skirt and top) Male (ankh, nemes, sandals and shendyt) or female (bun, sandals, shendyt and top) Male (headdress, loincloth, top and sandals) or female (headdress, loincloth, top and sandals)Ĭhangshan (male) or Cheongsam (female) outfitĬhangshan hat, jacket, shoes and trousers or Cheongsam headdress, shoes, skirt and top Male (ringlet, shirt, trousers and shoes) or female (ringlet, top skirt and shoes) Male (knot, robe, trousers and sandals) or female (bun, kimono, skirt and sandals) Male (head wrap, robe, trousers and shoes) or female (hood, robe, skirt and shoes) Male (tunic and leggings) or Female (blouse and skirt). Shade robes, formerly obtained from a random, are now dropped sometimes by Level 83 Shades in the Death level of the Stronghold of Security. These include Drill Demon camouflage, Freaky Forester lederhosen, Frog mask, Frog prince or princess outfit, Leo the Gravedigger zombie costume, and Mime outfit. This box holds all of your random event outfits. Helm, top, bottoms, gloves, boots, cape, amulet and ring.Ĭap, top, trousers OR skirt, gloves, and boots. Hat, helm, armour, skirt, gloves, cape and boots. Hood, top, bottoms, gloves, boots and cloak. The allowed sets include Ghostly robes, Infinity robes, Lunar armour, Moonclan armour, Mystic robes ( blue/white, white/gold, black/red), Skeletal armour (level 98 Wallasalki armour made by Peer the Seer), Splitbark armour, Dagon'Hai Robes, and all 4 sets of Mobilising Armies reward clothing. This wardrobe holds the best outfits for maging. For example, you can either store a cuisse or tassets with your initiate set, or you have to choose between storing an Armadyl-trimmed set with platelegs or a plateskirt. In addition, if the set has a choice between leg types, only one of them can be stored. That means you cannot store only your mime mask, or your Zamorak kiteshield - you must have the whole set. The main drawback to the Costume Room is that you can only store 1 of each item and a complete set of an outfit is required to store it. Additionally, all items must be removed from everything in the room before the room can be removed. To safeguard your precious items, you must remove them before you are allowed to remove any piece of furniture. All furniture may be built by the homeowner, or purchased as a flatpack from another player (great for getting those higher-level items). This guide is to help players decide which items they will want to handle their storage needs.īuilding a Costume Room requires level 42 Construction and costs 50,000 gp. The Costume Room is an unusual part of Construction because there are many restrictions and definitions as to how each piece of furniture can be used, however it is also one of the best ways to free up some space from an experienced member's bank. See Andrew from True Grit Texture Supply demonstrate Distress Press in his Affinity Creative Session over on our YouTube channel. Built from the ground up over a five-year period, every feature, tool, panel and function has been developed with the needs of creative professionals at its core. Create completely customized edge roughening and texture effects with full control of the level of detail and intensity of the effect Affinity Designer is the fastest, smoothest, most precise vector graphic design software around.Experiment with a huge variety of effects including high contrast grit, grunge, noise, paper grain, rubber stamp, letterpress, and natural woodtype.Designer users – brushes are raster format (not vector) and designed for use in Pixel Persona.One-click editing of distressed artwork color.I think that is locked into the brush when it was created. I dont think I can adjust the endpoints of the brush Im using. Looking at this further, maybe I will try to create my own brush. Non-destructive edge distressing leaves your original clean artwork intact I cannot find the adjustment that changes the distance the brush starts and ends from the corner.All brushes carefully crafted using real textures and optimized for use with drawing tablets.Comprehensive tutorial videos covering use of the distressing template and brushes to create custom distressing effects.4 x natural feel wood type letterpress effect brushes.10 x natural feel paper and subtle grain brushes with soft edges and textures that build up with each stroke In this video, I’m showing the process of working on a digital painting using Affinity Designer's default oil and gouache brushes.14 x high contrast speckle, grit, grunge, and grain brushes.1 x fully customizable distressing template and macros set for roughening the edges of your artwork, with complete control over detail and intensity of the effect. You’ll end up with authentic, effective results while saving time, strain and pain in the process. Distress Press by True Grit Texture SupplyĮlevate your work with these bespoke distressing and texture treatmentsįeaturing a customizable roughening template and incredible selection of pro-quality texture brushes, this kit from True Grit Texture Supply gives you the power to quickly create bespoke distressing and texture treatments for your artwork. |
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